Reburning
with Wood Fuels for NOx Mitigation
Reburning
is a combustion modification technology based on the principle
that hydrocarbon fragments (CH) can react
with Nitrogen Oxides (NOx). Reburning is accomplished by secondary
fuel injection downstream of the fuel-lean primary combustion
zone
or a furnace.
The second stage or reburning zone is usually operated at an
overall fuel-rich condition, allowing a significant fraction
of the primary NOx to be reduced to N2 and other nitrogenous
species. In the third zone, additional air is introduced to establish
overall fuel-lean conditions and allow for the burnout of remaining
fuel fragments.
Reburning studies with coal and natural gas have shown NOx emission
reductions of 50-60% with about 15% of the heat input coming
from the reburn fuel. In contrast, experimental results have
shown NOx reductions as high as 70% using approximately 10-15%
wood heat input.
The stoichiometric ratio in the reburn zone was the single most
important variable affecting NOx reduction. The highest reductions
were found at a reburn stoichiometric ratio of 0.85.
One additional benefit
of using wood instead of natural gas for reburning—it
is difficult to mix natural gas into the products of the primary
combustion zone since the gas must
be injected from the wall, at relatively low flows. Wood particles,
which must be transported to the furnace by a carrier medium
(likely candidates are air or flue gas), would have a ballistic
effect upon entering the furnace that would enhance cross-stream
mixing compared to natural gas.
Source: Brouwer,
J., N.S. Harding, M.P. Heap, J.S. Lighty, and D.W. Pershing,
1997, An Evaluation of Wood Reburning for NOx Reduction
from Stationary Sources, final report to the DOE/TVA Southeastern
Regional Biomass Energy Program, Muscle Shoals, AL, Contract
No. TV-92271 (available at www.bioenergyupdate.com).
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