Biofuels

Biofuels Overview

A variety of fuels can be produced from biomass resources including liquid fuels, such as, ethanol, methanol, biodiesel, Fischer-Tropsch diesel, and gaseous fuels, such as hydrogen and methane. Biofuels are primarily used to fuel vehicles, but can also fuel engines or fuel cells for electricity generation.

Fuels
Ethanol
Ethanol is made by converting the carbohydrate from biomass into sugar, which is then converted into ethanol in a fermentation process similar to brewing beer. Ethanol is the most widely used biofuel today with current capacity of 4.3 billion gallons per year based on starch crops, such as corn. Ethanol produced from cellulosic biomass is currently the subject of extensive research, development and demonstration efforts.

Biodiesel
Biodiesel is produced through a process in which organically derived oils are combined with alcohol (ethanol or methanol) in the presence of a catalyst to form ethyl or methyl ester. The biomass-derived ethyl or methyl esters can be blended with conventional diesel fuel or used as a neat fuel (100% biodiesel). Biodiesel can be made from any vegetable oil, animal fats, waste vegetable oils, or microalgae oils. Soybeans and Canola (rapeseed) oils are the most common vegetable oils used today.

BioOil
A totally different process than that used for biodiesel production can be used to convert biomass into a type of fuel similar to diesel which is known as BioOil. The process, called fast or flash pyrolysis, occurs when heating compact solid fuels at temperatures between 350 and 500 degrees Celcius for a very short period of time (less than 2 seconds). While there are several fast pyrolysis technologies under development, there are only two commercial fast pyrolysis technologies as of 2006. The BioOils currently produced are suitable for use in boilers for electricity generation. Additional research and development is needed to produce bioOil of sufficient quality for transportation applications.

Biofuels from Synthesis Gas
Biomass can be gasified to produce a synthesis gas composed primarily of hydrogen and carbon monoxide, also called syngas or biosyngas. Syngas produced today is used directly to generate heat and power but several types of biofuels may be derived from syngas. Hydrogen can be recovered from this syngas, or it can be catalytically converted to methanol. The gas can also be run through a biological reactor to produce ethanol or can also be converted using Fischer-Tropsch catalyst into a liquid stream with properties similar to diesel fuel, called Fischer-Tropsch diesel. However, all of these fuels can also be produced from natural gas using a similar process. Data on biofuels from synthesis gas are not currently included in the Biomass Data Book.

 

Source: U.S. Department of Energy, Energy Efficiency and Renewable Energy,
http://www.eere.energy.gov/RE/bio_fuels.html

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